The study aimed to identify the relationship of career adjustment with both social responsibility and work values and to find out the differences in the levels of career adjustment, social responsibility and work values according to the study variables. It also aimed at predicting the level of career adjustment through the dimensions of work values. The study used the descriptive correlative approach with three different questionnaires for the: career adjustment, social responsibility, and work values. The sample which was chosen by a clustered random way consisted of 215 specialists of career guidance from four governorates in the Sultanate of Oman, namely Al-Batinah North, Muscat, A'sharqiya South, and Dhofar. To answer the study questions, we used arithmetic averages, standard deviation, t- test for two independent samples, one way ANOVA analysis, and multiple linear regression analysis. The results showed that the sample possesses high levels of career adjustment with a general average (3.56) and work values with a general average (4.12), and a very high level of social responsibility with a general average (4.41). The results did not show a statistically significant difference in career adjustment, social responsibility and the work values attributed to the variables of gender, specialization, years of experience, and educational level. However, it showed that there are statistically significant differences in the levels of career adjustment due to the variable of the academic qualification in favour of the intermediate diploma versus the bachelor's and master's qualifications in the dimension of job satisfaction and the master's degree in the self-dimension and the scale in general. The differences came in favour of the bachelor versus the master in both the economic dimension and the scale In general, while there are no statistically significant differences at the level of significance (≤ 0,05) in ح both social responsibility and work values attributable to the variable of academic qualification. The results also showed that there are no statistically significant differences at the level of significance (≤ 0.05) in the levels of social responsibility attributed to the educational governorate variable between the governorates of Al Batinah North, Muscat, and Asharqiya South, while there are significant differences between Dhofar and the other governorates. There were no statistically significant differences in both career adjustment and work values attributable to the variable of the educational governorate. The results also showed a statistically significant correlation between all study variables. The results reached the possibility of predicting career adjustment through the dimensions of work values, namely: belonging to work, fairness in dealing and career control respectively, using the regression equation. Based on the results, the study came out with a set of recommendations and proposals, in order to serve the guidance and career guidance and educational field in general.